A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration.
نویسندگان
چکیده
A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.
منابع مشابه
Functionalized defects through solvent-assisted linker exchange: synthesis, characterization, and partial postsynthesis elaboration of a metal-organic framework containing free carboxylic acid moieties.
Intentional incorporation of defect sites functionalized with free carboxylic acid groups was achieved in a paddlewheel-based metal-organic framework (MOF) of rht topology, NU-125. Solvent-assisted linker exchange (SALE) performed on a mixed-linker derivative of NU-125 containing isophthalate (IPA) linkers (NU-125-IPA) led to the selective replacement of the IPA linkers in the framework with a ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 25 شماره
صفحات -
تاریخ انتشار 2009